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5,10,15,20-Tetrakis-(4-carboxyphenyl)-21,23H-porphine


Structure: (click to enlarge, please!)

Structure of 5,10,15,20-Tetrakis-(4-carboxyphenyl)-21,23H-porphine
Quantities Sold:  
1 g 80 €
2.5 g 175 €
5 g 320 €
10 g 575 €
Data:  
Synonym: TCPP
Part Number: PL00110100
CAS: 14609-54-2
Molecular Formula: C48H30N4O8
Molecular Weight: 790.7726
Melting Point: no information
Solubility: Water, Methanol, Ethanol, Pyridine

UV/VIS-Spectrum: (click to enlarge, please!)

spectrum of 5,10,15,20-Tetrakis-(4-carboxyphenyl)-21,23H-porphine

Informationen zum Einsatz von 

TCPP:

This porphyrin can for the simultaneous analysis of metals like Cu or Cd by HPLC. It is also possible to determine some heavy metals via UV / VIS spectroscopy with this ligand. Also in photodynamic tumor therapy (PDT) and tumor diagnosis, it finds its use. Furthermore, use in sensor technology (TNT detection) is possible.


Examples from the literature:

1.) Biesaga M., Pyrzynska K. and Trojanowicz M., Porphyrins in analytical chemistry. A review., Talenta, 51, 2000, 209-224
2.) Roales J., Pedrosa J. M., Guillén M. G., Lopes-Costa T., Castillero P., Barranco A. and González-Elipe A. R., Free-Base Carboxyphenyl Porphyrin Films Using a TiO2 Columnar Matrix: Characterization and Application as NO2 Sensors , Sensors, 15, 2015, 11118-11132
3.) Ahmadi E., Ramazani A., Hamdi Z., Mashhadi-Malekzadeh A. and Mohamadnia Z., 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin Covalently Bound to Nano-silica Surface: Preparation, Characterization and Chemosensor Application to Detect TNT, Silicon, 7, 2015, 323-332
4.) La D. D., Hangarge R. V., Bhosale S. V., Ninh H. D., Jones L. A. and Bhosale S. V. , Arginine-Mediated Self-Assembly of Porphyrin on Graphene: A Photocatalyst for Degradation of Dyes, Appl. Sci., 7 , 2017, 643