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Struktur: (zum Vergrößern bitte anklicken!)

Struktur von 5,10,15,20-Tetrakis-(4-carboxyphenyl)-21,23H-porphine
1 g 80 €
2.5 g 175 €
5 g 320 €
10 g 575 €
Kurzbezeichnung: TCPP
Bestellnummer PL00110100
CAS: 14609-54-2
Summenformel: C48H30N4O8
Molmasse: 790.7726
Schmelzpunkt: keine Angabe
Löslichkeit: Water, Methanol, Ethanol, Pyridine

UV/VIS-Spektrum: (zum Vergrößern bitte anklicken!)

Spektrum von 5,10,15,20-Tetrakis-(4-carboxyphenyl)-21,23H-porphine

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This porphyrin can for the simultaneous analysis of metals like Cu or Cd by HPLC. It is also possible to determine some heavy metals via UV / VIS spectroscopy with this ligand. Also in photodynamic tumor therapy (PDT) and tumor diagnosis, it finds its use. Furthermore, use in sensor technology (TNT detection) is possible.

Beispiele aus der Literatur:

1.) Biesaga M., Pyrzynska K. and Trojanowicz M., Porphyrins in analytical chemistry. A review., Talenta, 51, 2000, 209-224
2.) Roales J., Pedrosa J. M., Guillén M. G., Lopes-Costa T., Castillero P., Barranco A. and González-Elipe A. R., Free-Base Carboxyphenyl Porphyrin Films Using a TiO2 Columnar Matrix: Characterization and Application as NO2 Sensors , Sensors, 15, 2015, 11118-11132
3.) Ahmadi E., Ramazani A., Hamdi Z., Mashhadi-Malekzadeh A. and Mohamadnia Z., 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin Covalently Bound to Nano-silica Surface: Preparation, Characterization and Chemosensor Application to Detect TNT, Silicon, 7, 2015, 323-332
4.) La D. D., Hangarge R. V., Bhosale S. V., Ninh H. D., Jones L. A. and Bhosale S. V. , Arginine-Mediated Self-Assembly of Porphyrin on Graphene: A Photocatalyst for Degradation of Dyes, Appl. Sci., 7 , 2017, 643